Iodate reacts in the bisulfite-containing mixture. While bisulfite remains, iodine is consumed and the solution stays clear. Once that iodine-consuming reagent runs out, iodine accumulates and forms a dark blue complex with starch. The blue color is an indicator of that endpoint.
Increasing iodate concentration speeds up this model; increasing temperature makes a greater fraction of collisions energetic enough to react. The clock time is an inverse-rate proxy for comparing runs with a fixed amount of Solution B.
Model limits: This is an illustrative kinetics model, not a prediction of measured lab times. At 22 °C, 4.0 mL stock gives a 32 s clock. Time varies inversely with iodate concentration and follows an Arrhenius temperature factor (activation energy 45 kJ/mol). Solution B begins at 22 °C; mixing uses a volume-weighted temperature and assumes no subsequent heat loss. Bath conditioning is accelerated. No empirical calibration is supplied in the handout.
Solution B is the handout’s premix using 2% starch, 0.20 M sodium metabisulfite, and water; its internal proportions are not specified. The displayed concentration is for Solution A before adding B. Mixing dilutes it further by 16.0/22.4.